Why the "better" band depends on whether the signal has to cross open terrain or squeeze through a building — a single wavelength number drives both answers.
VHF (very high frequency, roughly 30–300 MHz — land mobile radio commonly uses 136–174 MHz) and UHF (ultra high frequency, roughly 300 MHz–3 GHz — LMR commonly uses 380–512 MHz and 700/800/900 MHz public-safety bands) aren't just two labeled dials on a radio. The frequency difference sets a real, physical wavelength difference, and that wavelength is what actually decides how a signal behaves once it leaves the antenna — how far it carries across open ground, how well it diffracts around hills and tree lines, and how easily it slips through windows, wall cavities, and stairwells once it reaches a building.