Worked problem

Mixing Two Solutions: Flow and Concentration

Mix two streams of different flow and solute mass fraction with a steady-state mass balance, and find the flow of stream B for a 20% mixture.

Chemical & Process · Last reviewed

Given

Stream A: 800 kg/h at 10% solute by mass. Stream B: 500 kg/h at 40% solute by mass. The two streams mix in a tank with no reaction and no accumulation (steady state). Concentrations are mass fractions.

Find

The mixed-stream flow and its solute mass fraction. Then, the flow of stream B that would give a 20% mixture with 800 kg/h of stream A.

Solution

  1. Total mass balance: 800 + 500 = 1,300 kg/h leaves the mixer.
  2. Solute balance: solute in = 800 × 0.10 + 500 × 0.40 = 80 + 200 = 280 kg/h. All of it leaves in the mixed stream.
  3. Mixed mass fraction = 280 ÷ 1,300 = 0.2154, or 21.5% solute.
  4. For a 20% mixture: 80 + 0.40 × B = 0.20 × (800 + B), so 0.20 × B = 80 and B = 400 kg/h.

Answer

1,300 kg/h at 21.5% solute | 400 kg/h of stream B gives 20%

The mixture is a weighted average

The mixed concentration lies between the two inlet concentrations, closer to the one with the larger flow. Here it is 10% + (500 ÷ 1,300) × 30% = 21.5%. Averaging the two percentages without weights would give 25%, which is wrong because the streams are not equal.

Common mistakes

  • Averaging the concentrations without weighting them by the flow rates.
  • Adding volume flows when the solution densities differ. Mass is conserved, volume is not exactly.
  • Mixing mass fractions with mole fractions, or percent by weight with percent by volume.
  • Forgetting that the solute balance and the total balance are two equations from which both unknowns follow.

Related tools and labs

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Questions

Why is mass used instead of volume?

Mass is conserved in mixing. Volumes of liquid mixtures are often not additive, so mass balances are safer.

What if a reaction or heat effect happens on mixing?

The mass balance still holds, but the temperature and possibly the species change. An energy balance or a reaction term is then needed.

What does steady state mean here?

The flows and concentrations do not change with time, so the tank holds a constant amount and what comes in equals what goes out.

Educational material. Examples use simplified, hypothetical inputs and are not a design, a construction document or professional engineering advice. Confirm requirements with the codes and standards adopted where the work is built and with a licensed engineer.

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