First: What "PE Interview" Does and Doesn't Mean

If you searched for "PE interview questions" expecting to prepare for a formal oral licensing exam, it's worth clearing this up before anything else: US Professional Engineer licensure does not have an interview component. Licensure is exam-based — you take the NCEES PE exam, a proctored, computer-based test scored against a fixed passing standard, administered by your state licensing board through NCEES. There is no oral defense, no panel, no "PE interview" you sit for as part of becoming licensed, in any US state.